Thematic Articles

Noble Gas Thermochronology of Extraterrestrial Materials

Rocks from extraterrestrial bodies in the Solar System are influenced by thermal processes occurring within planetary interiors and on their surfaces. These range from the extremely hot and brief, in the case of impact events, to the comparatively cool and protracted, in the case of solar irradiation of rocks residing in regoliths for millions to billions of years. Noble gas thermochronology applied to meteorites and extraterrestrial materials returned by space missions enables us to decipher the histories of these materials and thereby understand fundamental aspects of the evolution of terrestrial planetary bodies, including the Moon, Mars, and asteroids.

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Vestiges of the Ancient: Deep-Time Noble Gas Thermochronology

Ancient rocks have survived plate tectonic recycling for billions of years, but key questions remain about how and when they were exhumed to the surface. Constraining exhumation histories over long timescales is a challenge because much of the rock record has been lost to erosion. Argon and helium noble gas thermochronology can reconstruct deep-time <350 °C thermal histories by using the distinct temperature sensitivities of minerals such as feldspar, zircon, and apatite, while exploiting grain size and radiation damage effects on diffusion kinetics. Resolution of unique time–temperature paths over long timescales requires multiple chronometers, appropriate kinetic models, and inverse simulation techniques to fully explore and constrain possible solutions. Results suggest that surface histories of ancient continental interiors are far from uninteresting and may merely be misunderstood.

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Iron Oxide (U–Th)/He Thermochronology: New Perspectives on Faults, Fluids, and Heat

Fault zones record the dynamic motion of Earth’s crust and are sites of heat exchange, fluid–rock interaction, and mineralization. Episodic or long-lived fluid flow, frictional heating, and/or deformation can induce open-system chemical behavior and make dating fault zone processes challenging. Iron oxides are common in a variety of geologic settings, including faults and fractures, and can grow at surface- to magmatic temperatures. Recently, iron oxide (U–Th)/He thermochronology, coupled with microtextural and trace element analyses, has enabled new avenues of research into the timing and nature of fluid–rock interactions and deformation. These constraints are important for understanding fault zone evolution in space and time.

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Earth’s Dynamic Past Revealed by Detrital Thermochronometry

Advances in detrital noble gas thermochronometry by 40Ar/39Ar and (U–Th)/He dating are improving the resolution of sedimentary provenance reconstructions and are providing new insights into the evolution of Earth’s surface. Detrital thermochronometry has the ability to quantify tectonic unroofing or erosion, temporal and dynamic connections between sediment source and sink, sediment lag-times and transfer rates, the timing of deposition, and postdepositional burial heating. Hence, this technique has the unique ability to use the detrital record in sedimentary basins to reconstruct Earth’s dynamic long-term landscape evolution and how basins are coupled to their hinterlands.

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Noble Gases Deliver Cool Dates from Hot Rocks

Heat transfer in the solid Earth drives processes that modify temperatures, leaving behind a clear signature that we can measure using noble gas thermochronology. This allows us to record the thermal histories of rocks and obtain the timing, rate, and magnitude of phenomena such as erosion, deformation, and fluid flow. This is done by measuring the net balance between the accumulation of noble gas atoms from radioactive decay and their loss by temperature-activated diffusion in mineral grains. Together with knowledge about noble gas diffusion in common minerals, we can then use inverse models of this accumulation–diffusion balance to recover thermal histories. This approach is now a mainstream method by which to study geodynamics and Earth evolution.

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Fluids in Geothermal Systems

Hot fluids are nearly ubiquitous in volcanic environments in the Earth’s crust. Magma at depth heats groundwater which then ascends towards the Earth’s surface through faults, fractures, and otherwise permeable rocks. Fluids in geothermal systems offer direct insight into the many complex chemical and physical processes that occur in these extreme environments. They are also analogues of many ore-forming systems. Scientists have advanced our understanding of fluids in geothermal systems by studying wells sunk ~2–3 km deep into many geothermal fields. Today, we are targeting deeper and hotter reservoirs, at or near the contact of magmatic bodies, which provide unique opportunities to study, and potentially utilize, supercritical fluid resources in the near future.

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Magmatic-Hydrothermal Fluids

Magmatic-hydrothermal fluids play a key role in a variety of geological processes, including volcanic eruptions and the formation of ore deposits whose metal content is derived from magmas and transported to the site of ore deposition by means of hydrothermal fluids. Here, we explain the causes and consequences of fluid saturation in magmas, the corresponding fluid-phase equilibria, and the behavior of metals and ligands during the transition from magma to an exsolved hydrothermal fluid. Much of what we know about magmatic-hydrothermal systems stems from the study of fluid inclusions, which are minute droplets of fluids trapped within minerals during mineral growth.

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Subduction-Zone Fluids

Fluids are essential to the physical and chemical processes in subduction zones. Two types of subduction-zone fluids can be distinguished. First, shallow fluids, which are relatively dilute and water rich and that have properties that vary between subduction zones depending on the local thermal regime. Second, deep fluids, which possess higher proportions of dissolved silicate, salts and non-polar gases relative to water content, and have properties that are broadly similar in most subduction systems, regardless of the local thermal structure. We review key physical and chemical properties of fluids in two key subduction-zone contexts—along the slab top and beneath the volcanic front—to illustrate the distinct properties of shallow and deep subduction-zone fluids.

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Fluids in Submarine Mid-Ocean Ridge Hydrothermal Settings

Metamorphic reactions within the Earth’s crust produce fluids of variable composition that play a major role in the evolution of continents. Metamorphic fluids facilitate reactions that alter crustal rheology, reduce melting temperature, cycle elements between geological reservoirs and form ore deposits. These fluids are relatively inaccessible, other than by study of fluid inclusions, so most studies rely on a combination of indirect evidence and predictive thermodynamic models to determine the characteristics and roles of the fluids. In this article, the origins, compositions, controlling phase equilibria, and roles of metamorphic fluids are reviewed, followed by a discussion of selected areas of current and future research.

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Metamorphic Fluids in Orogenic Settlings

Metamorphic reactions within the Earth’s crust produce fluids of variable composition that play a major role in the evolution of continents. Metamorphic fluids facilitate reactions that alter crustal rheology, reduce melting temperature, cycle elements between geological reservoirs and form ore deposits. These fluids are relatively inaccessible, other than by study of fluid inclusions, so most studies rely on a combination of indirect evidence and predictive thermodynamic models to determine the characteristics and roles of the fluids. In this article, the origins, compositions, controlling phase equilibria, and roles of metamorphic fluids are reviewed, followed by a discussion of selected areas of current and future research.

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