Thematic Articles

Stable Isotopes as Tracers of Anthropogenic Nitrogen Sources, Deposition, and Impacts

The global nitrogen cycle has been perturbed by human activities, including agriculture, land-use change, and fossil fuel burning. This perturbation ranges from the local to global scale, as anthropogenic reactive nitrogen can be transported over long distances in the atmosphere, in groundwater, and in stream networks and can even impact the open ocean. Stable isotope signatures characteristic of reactive nitrogen can be used to trace its deposition in the present day, as well as in the past. Here we focus on the use of stable isotopes to trace the sources, transport, and impacts of anthropogenic nitrogen in the modern nitrogen cycle.

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Nitrogen: Highly Volatile yet Surprisingly Compatible

Nitrogen exhibits an intriguing combination of highly volatile behavior (particularly as N2), appreciable reactivity, and surprising compatibility in the deep Earth. Nitrogen is incorporated into the biosphere and then, through diagenesis and low-grade metamorphism, is conveyed into the lithosphere and the deeper Earth. The investigation of N behavior in the biosphere, hydrosphere, and atmosphere has led to many important discoveries regarding biogeochemical pathways, including in areas such as trophic interactions and anthropogenic impacts on terrestrial and marine environments (e.g. nutrient pollution, eutrophication). Nitrogen can act as an excellent tracer of the transfer of sedimentary/organic materials into and within deep-Earth reservoirs and shows great potential as a tracer of life on early Earth and elsewhere in the Solar System.

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Formation and Exhumation of Ultrahigh-Pressure Terranes

The reigning paradigm for the formation and exhumation of continental ultrahigh-pressure (UHP) terranes is the subduction of crust to mantle depths and the return of crustal slices within the subduction channel— all at plate tectonic rates. Additional processes beyond the paradigm are needed to explain the diversity of geological observations gathered from the growing study of UHP terranes—for example, variations in the size, degree of deformation, petrologic evolution, timing of UHP metamorphism, and exhumation rates. Numerical models that evaluate physical parameters in time and space have produced new insights into the formation and exhumation of UHP terranes.

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Deep Fluids in Subducted Continental Crust

Establishing the timing and duration of ultrahigh-pressure metamorphism (UHP) for crustal rocks subducted to mantle depths of over 100 km requires high-precision geochronology directly coupled with pressure-sensitive indicators. The best links between UHP conditions and an age estimate are inclusions of the UHP indicator minerals coesite and/or diamond in datable zircon or garnet. Lu–Hf and Sm–Nd garnet ages define the prograde and peak portions of the pressure–temperature path for cold (<700 ºC), fast (>1 cm/y) UHP systems. UHP metamorphism in hotter (>800 ºC) and slower (<1 cm/y) terranes is best dated by U–Pb analysis of coesite-bearing zircon domains coupled with Sm–Nd and Lu–Hf garnet analysis.><1 cm/y) terranes is best dated by U–Pb analysis of coesite-bearing zircon domains coupled with Sm–Nd and Lu–Hf garnet analysis.

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Linking Time to the Pressure–Temperature Path for Ultrahigh-Pressure Rocks

Establishing the timing and duration of ultrahigh-pressure metamorphism (UHP) for crustal rocks subducted to mantle depths of over 100 km requires high-precision geochronology directly coupled with pressure-sensitive indicators. The best links between UHP conditions and an age estimate are inclusions of the UHP indicator minerals coesite and/or diamond in datable zircon or garnet. Lu–Hf and Sm–Nd garnet ages define the prograde and peak portions of the pressure–temperature path for cold (<700 ºC), fast (>1 cm/y) UHP systems. UHP metamorphism in hotter (>800 ºC) and slower (<1 cm/y) terranes is best dated by U–Pb analysis of coesite-bearing zircon domains coupled with Sm–Nd and Lu–Hf garnet analysis.><1 cm/y) terranes is best dated by U–Pb analysis of coesite-bearing zircon domains coupled with Sm–Nd and Lu–Hf garnet analysis.

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Constructing the Pressure–Temperature Path of Ultrahigh-Pressure Rocks

Coesite and diamond in metamorphic rocks point to their very deep burial, but these minerals do not allow a precise derivation of metamorphic pressure–temperature (P–T) conditions at ultrahigh pressure (UHP). Thermodynamic calculations of mineral equilibria can accomplish this task when it is possible to assign mineral compositions to a former UHP equilibrium state. Pressure–temperature pseudosections are superior, because they often permit the construction of P–T paths to and from UHP conditions only on the basis of chemically zoned minerals such as garnet and phengite. The examples of a metapelite from Oman and an eclogite from the Erzgebirge, Germany, illustrate this method, but also demonstrate its limits. The derived paths are the basis for further geodynamic modeling and insight into tectonic processes.

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Continental Crust at Mantle Depths: Key Minerals and Microstructures

Finding evidence for ultrahigh-pressure (UHP) metamorphism in crustal rocks is far from straightforward. The index minerals coesite and diamond are incredibly inconspicuous and are therefore difficult to use as UHP prospecting tools. Consequently, petrographers rely on recognizing subtle breakdown microstructures that result from pressure release during the return to the surface of the once deeply buried rock. Similarly, many other UHP minerals are first suspected on the basis of typical reaction or exsolution microstructures. Thus, the painstaking use of microscopic techniques has been fundamental to the tremendous advances in characterizing, quantifying, and understanding macroscopic-scale, deep continental subduction, rapid exhumation, and mountain-building processes.

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The Realm of Ultrahigh Pressure Metamorphism

The discovery of diamond and coesite in crustal rocks is compelling evidence that continental material has experienced pressures that can only be achieved at mantle depths. At least 20 terranes of unequivocal continental crust containing diamond or coesite are now recognized around the globe; their study constitutes a new field in petrology called ultrahigh-pressure metamorphism. The idea that continents do not subduct has given way to the notion that Earth has been sufficiently cool since the Cryogenian (~850 Ma) to allow density changes to drive continental crust into the mantle during collision. Some of this crust is exhumed to the surface, some pools at the Moho, and the rest sinks into the mantle. In this issue, microscopic observations, phase-equilibrium modeling, geochronology, and geodynamic modeling track the journey of crustal rocks to the mantle and back to Earth’s surface.

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Virtual Probes of Mineral–Water Interfaces: The More Flops, the Better!

New approaches are allowing computer simulations to be compared quantitatively with experimental results, and they are also raising new questions about reactivity at mineral–water interfaces. Molecular simulations not only help us to understand experimental observations, they can also be used to test hypotheses about the properties of geochemical systems. These new approaches include rigorous calibration of simulation models against thermodynamic properties and atomic structure. They also encompass rare event theory methods that allow simulation of slow, complex mineral surface reactions. Here, we give an overview of how these techniques have been applied to simulate mineral–water interface structure, growth/ dissolution mechanisms, and cluster formation.

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Control of Crystal Nucleation and Growth by Additives

The survival of important pieces of our architectural and sculptural heritage is challenged by irreparable damage due to crystallization of soluble salts. Mineral precipitation is also a problem in many industrial processes, leading to costly scale formation. Most of the mechanisms that control these crystallization reactions can be modified or slowed down by using specific additives. Recent advances in elucidating the mechanisms of mineral nucleation and growth and molecular-level mineral–additive interactions have led to the development of novel treatments for the prevention of mineral scale and salt damage.

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December 2025 --The Variscan Orogeny in Europe – Understanding Supercontinent Formation

The Variscan orogen formed between 380 and 300 million years ago through several accretionary and collisional cycles, culminating with the construction of the Pangea supercontinent. This process occurred via sequential opening and closure of oceanic basins, synchronous detachment of Gondwana derived continental ribbons, and their outboard amalgamation onto the Laurussia margin. The Variscan orogen is rather unique compared with other orogenic belts on Earth: its overthickened and dominantly magmatic crust in the central belt, surprisingly minor mantle involvement in the magmatic and geodynamic processes, coherent and pulsed magmatism along the collision suture, and its complex accretionary history. Because its final product, Pangea, is the youngest and best-understood supercontinent on Earth, the Variscan orogeny offers clues for understanding the mechanisms of supercontinent formation.