Thematic Articles

Diversity of Complex Organic Matter in Carbonaceous Chondrites, IDPs, and UCAMMs

Complex organic matter is present in many extraterrestrial materials such as chondrite meteorites, micrometeorites, and interplanetary dust. The observed complexity of this organic matter is due to the combination of diversity of primitive organic materials that accreted onto asteroids and the subsequent effect of hydrothermal and/or metamorphic alteration that took place after accretion. These processes resulted in a variety of carbonaceous grain morphologies, elemental abundances, and organic functional group compositions. Some carbonaceous dust grains and micrometeorites have cometary origins and provide insights into the unique processing histories on those outer Solar System bodies. Isotopic analyses can help distinguish carbonaceous grains that retain their pre-accretion heritage, while advanced microscopy techniques reveal the interplay of complex organic matter with surrounding mineral.

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Delivery of Organic Matter to the Early Earth

The inner Solar System—including the planet Earth—was heavily bombarded by comets, asteroids, and their fragments (i.e., meteorites, micrometeorites, and interplanetary dust particles) from 4.56 to about 3.5 billion years ago. This bombardment resulted in a rich assortment of organics delivered to the Earth, as comets and many asteroids contain carbonaceous material. These organic compounds were likely further processed on the early Earth (e.g., by impact-shock reactions), providing a feedstock of prebiotic molecules to the crust and oceans. In this chapter, we review the mechanisms of organic matter delivery to the primitive Earth, further reactions and processing, and the importance of exogenous material in the evolution of our planet and life.

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Formation and Evolution Mechanisms for Organic Matter in Space

Organic compounds are a major component of dust in molecular clouds, alongside silicates and water ice, due to the high abundances of elements that make up these compounds in the Galaxy. The initial molecular inventory of the Solar System, inherited from the molecular cloud, was modified and new complex molecules were formed in the protoplanetary disk and planetesimals. Because astronomical observations mainly target gas, while cosmochemical evidence deals with solid phases, it is crucial to link discrepant knowledge on organic species through state-of-the-art modeling. This chapter reviews the latest understanding of surface reactions on inter- stellar dusts, gas–dust reactions in the protoplanetary disk, and alteration processes on planetesimals in the early Solar System.

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Extraterrestrial Organic Matter: An Introduction

Extraterrestrial organic matter forms in a variety of locations in space through different mechanisms. Its nature, distribution, formation mechanisms and locations are of particular interest. Some organic molecules can even be considered as key players for the emergence of life. Although new organic species are continuously detected in the interstellar media, Solar System bodies, and extraterrestrial materials, their formation and evolution are still not fully understood. Ground-based and space observations can detect organic matter in different objects with a range of complexity and diversity, while laboratory investigations of astromaterials allow detailed characterization of extraterrestrial organic matter with high precision. This issue reviews different aspects of extraterrestrial organic matter, including its origin, evolution, diversity, and delivery.

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Uncertainty and Value: Optimising Geometallurgical Performance Along the Mining Value Chain

To maximise the value of a mining operation and minimise its environ- mental and social impacts, all processes—from the ore deposit to the final product and waste streams—should be optimised together. However, mining and metallurgical processes are inherently variable and uncertain due to the natural heterogeneity of ore deposits and the limited information and incomplete models available on ore behaviour throughout the process chain. Propagating these effects to geometallurgical models is important because they are used to make decisions with potentially large environmental and economic impacts. In this paper, we describe the need for geometallurgical optimisation routines to account for the effects of uncertainties, and the tools needed to manage them, by summarising the routines that already exist and those that are still missing.

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Action Versus Reaction: How Geometallurgy Can Improve Mine Waste Management Across the Life-Of-Mine

The raw materials industry produces billions of tonnes of mine waste per year. Given increasing metal demand and the global appetite for waste reduction, strategic opportunities to minimise its production must be embedded across the life-of-mine. Adopting a geometallurgical approach to total deposit characterisation—where mineralogical and geochemical data are routinely collected and used to model geoenvironmental domains—offers profound benefits for improving the understanding of the composition and environmental impact of different residues. Using established and emerging technologies, from handheld instruments and core scanners to synchrotrons, throughout a mine’s life—starting already during exploration—may assist the raw materials industry to reduce their waste footprint and adopt circular economy principles.

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Fire and Water: Geometallurgy and Extractive Metallurgy

There is no doubt that mineralogy, texture, and microfabric, as primary characteristics of an ore, affect mineral processing operations. Their direct effects on extractive metallurgical processes and the associated optimization potential, however, are less well documented. Here, we examine the status of geometallurgical approaches in extractive metallurgy by focusing on the effects of primary ore characteristics in hydrometallurgical and pyrometallurgical processes. Two selected case studies illustrate the linkages. Using quantitative data analytics on ores and concentrates, the possibilities for optimized and sustainable metal extraction and waste valorization are discussed.

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All About Particles: Modelling Ore Behaviour in Mineral Processing

Mineral processing encompasses the series of operations used to first liberate the valuable minerals in an ore by comminution, and then separate the resulting particles by means of their geometric, compositional, and physical properties. From a geometallurgical perspective, it is fundamental to understand how ore textures influence the generation of ore particles and their properties. This contribution outlines the processes used to generate and concentrate ore particles, and how these are commonly modelled. A case study illustrates the main ideas. Finally, a brief outlook on the most important research challenges remaining in this branch of geometallurgy is presented.

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Characterization of Ore Properties for Geometallurgy

The successful implementation of geometallurgy largely depends on the continuous collection of high-quality, multi-scale, multi-dimensional quantitative data on the geology, geochemistry, mineralogy, texture, and physical properties of an orebody. This can then be used to build and improve, amongst other things, ore deposit models, comminution strategies, waste management, and downstream mineral processing and extractive metallurgy routes. The present contribution provides a brief overview of the key types of data collected, and analytical techniques used, in geometallurgical programs. It also highlights important developments that are currently underway, which may generate a significant impact in the near future.

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Geometallurgy: Present and Future

Geometallurgy is an interdisciplinary research field concerned with the planning, monitoring, and optimisation of mineral resource extraction and beneficiation. Geometallurgy relies on a quantitative under- standing of primary resource characteristics such as mineralogical composition and texture, the spatial distribution and variability of these characteristics, and how they interact with mining and beneficiation processes. Thus, geometallurgy requires accurate analytical data for resource characterisation and detailed models of orebody geology, mining and processing technologies, mineral economics, and the often-complex interactions between them. Here, we introduce the fundamental concepts relevant to the field, with particular emphasis on the current state-of-the-art and some notes on potential future developments.

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