Thematic Articles

Arsenic

Arsenic is an element known throughout history as a classic poison. Currently, very small but highly significant concentrations of this element in drinking water supplies are causing massive health problems to many millions of people in some of the world’s poorest nations. More localised sources related to mining and processing are also a concern. A review of background information on arsenic chemistry, occurrence in the Earth, production and uses, as well as its toxic properties, leads in to the other articles in this issue of Elements.

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New Opportunities at Emerging Facilities

Synchrotron X-ray sources and pulsed neutron sources are getting brighter. This permits new opportunities for scattering, spectroscopy, and imaging studies of Earth materials and processes that were not possible a decade ago. The impact of these latest-generation facilities on Earth sciences research requiring nanometer- to micrometer-scale resolution is growing and will continue to grow as next-generation X-ray and neutron sources become available over the next six years. These facilities will include the world’s first X-ray free-electron lasers in the US (2009) and Europe (2012) and the Spallation Neutron Source at Oak Ridge National Laboratory, USA (2006). In addition, five nanoscale science research centers are under con- struction in the US and will impact the emerging field of nanogeoscience.

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Accessing User Facilities and Making Your Research Experience Successful

Access to many of the world’s leading user facilities is easier than ever before, with web-based tutorials providing everything from instru- mental overviews and example applications to online safety training. Submission of proposals for experiment time at large, heavily subscribed facilities, including synchrotron and neutron sources, has been streamlined with web-based submission. Support, which is commonly the key to successful experiments, is provided by facility staff and experienced users, allowing new users to begin experiments with minimal experience. Increasingly Earth scientists are taking advantage of the wide range of unique instrumentation at user facilities. Here, we explain how you can, too.

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Scientific Advances Made Possible by User Facilities

National scientific user facilities are becoming increasingly available to many different scientific communities in a number of countries. There is a growing use of these facilities by Earth and environmental scien- tists to study a broad range of materials and processes under realistic P–T and environmental conditions at unprecedented levels of energy and spatial resolution and elemental and isotopic sensitivity. The results of these studies are providing new insights into biogeochemical processes operating at Earth’s surface as well as petrological, geochemical, and geophysical processes in Earth’s interior. The availability of national user facilities is changing scien- tific approaches and is leading to multidisciplinary studies that were not possible a decade ago.

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Synchrotron Radiation, Neutron, and Mass Spectrometry Techniques at User Facilities

User research facilities around the world offer tremendous opportunities for scientific experimentation by members of the Earth science com- munity. Synchrotron radiation sources, neutron sources, mass spec- trometers, and others represent a powerful force in tackling complex scien- tific problems. In these techniques, Earth materials are bombarded with beams of ions, subatomic particles and/or photons to learn the secrets of their properties and histories. Some of these methods can be applied to nanoscale materials with “desktop” instruments while others require macro- scopic samples and utilize large-scale devices residing in multiple buildings; and there is everything in between.

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User Facilities around the World

National and international communities of scientists from a variety of disciplines have been successful in convincing a growing number of countries to construct major user facilities that collectively serve these communities. These user facilities make possible experimental studies that cannot be done in individual investigator laboratories. In addition, they have created a new style of research, in which scientists working in shared facilities conduct studies that benefit from a merging of ideas and techniques from different disciplines. Earth science users of these facilities are growing in number and are benefiting greatly from the multidisciplinary interactions such facilities stimulate and from the unique experimental capabilities they provide.

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User Research Facilities in the Earth Sciences

The past several decades have seen an explosion in the availability of state-of-the-art research facilities, facilities that have been specifically constructed and operated for use by the general scientific community. Earth scientists have recognized the power of these methods for frontier research and are taking advantage of them in increasing numbers. “User- friendliness” is the key that makes these shared instruments very effective components in our arsenal of collaborative and interdisciplinary research tools.

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The Link between Large Igneous Province Eruptions and Mass Extinctions

In the past 300 million years, there has been a near-perfect association between extinction events and the eruption of large igneous provinces, but proving the nature of the causal links is far from resolved. The asso- ciated environmental changes often include global warming and the develop- ment of widespread oxygen-poor conditions in the oceans. This implicates a role for volcanic CO2 emissions, but other perturbations of the global carbon cycle, such as release of methane from gas hydrate reservoirs or shut-down of photosynthesis in the oceans, are probably required to achieve severe green- house warming. The best links between extinction and eruption are seen in the interval from 300 to 150 Ma. With the exception of the Deccan Trap eruptions (65 Ma), the emplacement of younger volcanic provinces has been generally associated with significant environmental changes but little or no increase in extinction rates above background levels.

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Oceanic LIPs: The Kiss of Death

Oceanic plateaus represent large areas (~1 ×× 106 km2) of thickened oceanic crust formed from rapidly erupted lava (<3 Myr). These plateaus have formed throughout most of geological time. They generally correlate with periods of environmental catastrophe characterised by oceanic anoxia, leading to black shale formation and mass extinction events. Such correlations are particularly evident in the Cretaceous and can be partly attributed to the release of CO2 during oceanic plateau formation, which ultimately resulted in a runaway greenhouse effect. Additionally, sea level rise and disruption of oceanic circulation patterns by displacement of seawater during plateau formation contributed to increased environmental stress and biotic extinction.

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Gas Fluxes from Flood Basalt Eruptions

Subaerial continental flood basalt volcanism is distinguished from all other volcanic activity by the repeated effusion of huge batches of basaltic magma (~102–103 km3 per eruption) over short periods of geologic time (<1 Myr). Flood basalt provinces are constructed of thick stacks of extensive pahoehoe-dominated lava flow fields and are the products of hundreds of eruptions. Each huge eruption comes from a dyke-fed fissure tens to hundreds of kilometres long and lasts about a decade or more. Such spatial and temporal patterns of lava production do not occur at any other time in Earth history, and, during eruptions, gas fluxes of ~1 Gt per year of SO2 and CO2 over periods of a decade or more are possible. Importantly, the atmospheric cooling associated with aerosols generated from the SO2 emis- sions of just one flood basalt eruption is likely to have been severe and would have persisted for a decade or longer. By contrast, warming due to volca- nogenic CO2 released during an eruption is estimated to have been insignifi- cant because the mass of CO2 would have been small compared to that already present in the atmosphere.

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December 2025 --The Variscan Orogeny in Europe – Understanding Supercontinent Formation

The Variscan orogen formed between 380 and 300 million years ago through several accretionary and collisional cycles, culminating with the construction of the Pangea supercontinent. This process occurred via sequential opening and closure of oceanic basins, synchronous detachment of Gondwana derived continental ribbons, and their outboard amalgamation onto the Laurussia margin. The Variscan orogen is rather unique compared with other orogenic belts on Earth: its overthickened and dominantly magmatic crust in the central belt, surprisingly minor mantle involvement in the magmatic and geodynamic processes, coherent and pulsed magmatism along the collision suture, and its complex accretionary history. Because its final product, Pangea, is the youngest and best-understood supercontinent on Earth, the Variscan orogeny offers clues for understanding the mechanisms of supercontinent formation.