Thematic Articles

Stable Isotopes and the Origin of Diamond

Most diamonds form in a relatively narrow depth interval of Earth’s subcontinental mantle between 150 and 250 km. From carbon isotope analyses of diamond obtained in the 1970s, it was first proposed that eclogitic diamonds form from crustal carbon recycled into the mantle by subduction and that the more abundant peridotitic diamonds formed from mantle carbon. More recent stable isotope studies using nitro- gen, oxygen, and sulfur, as well as carbon, combined with studies of mineral inclusions within diamonds, have strengthened arguments supporting and opposing the early proposal. The conflicting evidence is reconciled if mantle carbon is introduced via fluid into mantle eclogites and peridotites, some of which represent subducted oceanic crust.

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Inclusions in Sublithospheric Diamonds: Glimpses of Deep Earth

Diamonds originate in the deep roots of ancient continental blocks (cratons) that extend into the diamond stability field beneath about 140 km. Over the last two decades, rare diamonds derived from even greater depths—the deep upper mantle, the transition zone (410–660 km), and the lower mantle—have been recognized. Inclusions in diamonds from the deep upper mantle and the transition zone document sources of basaltic composition, possibly related to subduction of old oceanic crust back into Earth’s mantle. Diamonds from the lower mantle carry inclusions that largely confirm predictions of the composition and mineralogy of the deep mantle based on a “pyrolite” (primitive peridotitic) composition of silicate Earth. For some inclusions, however, the chemical evidence again points to a connection with subducting oceanic slabs, possibly ponding at the top of the lower mantle.

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Diamonds

Active research on diamond, a carbon mineral with superlative proper- ties, extends into many realms of natural and material sciences. Extreme hardness and transparency make diamond a valuable gem and a high-pressure research tool, as well as a superabrasive. Natural forma- tion at high pressure and resistance to weathering make diamonds our most informative messengers from Earth’s mantle. A review of diamond’s charac- ter and forms leads into the topics of the articles in this issue of Elements.

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Extraterrestrial Water

Abundant water ice was formed in the solar nebula outward of about 4 astronomical units and, during the entire history of the solar system, has been carried into the inner solar system in icy and hydrated bodies. We do not know which sources of water dominated in the inner solar system, but micrometeorites derived from C-class asteroids may have been most important. Today, hydrous materials occur throughout the solar system from Jupiter inwards, at least. Significant quantities of liquid water are, however, probably present only on Earth and some icy moons of Jupiter and possibly Saturn.

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Fluids, Faulting, and Flow

Geological fluids affect deformation of rocks both physically and chemically. The presence of fluids can lead to faulting (earthquakes) or enhance flow, depending on the level of stress. At higher stresses, fluids with a density less than their host generate Mode I microcracks, whereas fluids with a density greater than their host generate Mode I microanticracks; both can self-organize and cause faulting. At lower stresses, fluids segregate to grain boundaries at small strains and, at large strains, fluid-enriched zones develop that experience a higher strain rate than the bulk. Dissolved H2O enhances flow (e.g., by water-weakening). Consequences include earthquakes, differentiation, melt separation/volcanism, and seismic anisotropy.

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Water in the Mantle

Subducting slabs transport water stored in hydrous minerals into the transition zone and lower mantle. The water storage capacity of the upper and lower mantles is less than 0.2 wt%. The transition zone has a storage capacity of approximately 0.5–1 wt% due to a water solubility of about 1–3 wt% in wadsleyite and ringwoodite, which are the major con- stituents of the transition zone. Thus, the transition zone may be a major water reservoir in the Earth’s interior. Recent geophysical observations suggest the existence of the hydrated transition zone beneath subduction zones. Water or hydrogen may be transported as far as the bottom of the lower mantle by reacting with metallic iron in the lower mantle to form hydrous phases or iron hydride.

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Volatiles in Magmatic-Volcanic Systems

The abundance and flux of volatiles are important to the hazards associated with explosive volcanic eruptions. Volatiles in magmas can be determined from investigations of melt and fluid inclusions in combination with volatile solubility data. A comparison of the newly deter- mined solubilities of H 2O, SO2, and Cl in a molten Vesuvius phonolite with the compositions of Mt. Somma-Vesuvius melt and fluid inclusions further elucidates degassing and eruptive processes for this volcano.

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Ore-Forming Fluids

Ore-forming (hydrothermal) fluids, consisting largely of H 2O, CO2, and NaCl, formed most of Earth’s ore deposits. The fluids exist as largely unconfined systems in meteoric, seawater, and basinal settings, or locally and intermittently confined systems in magmatic, metamorphic, and basinal settings, and they are driven largely by differences in temperature, elevation or density. Temperatures are highest (~600°C) in magmatic and lowest in basinal and meteoric (~100°C) systems. Salinities well above that of seawater are reached by boiling, evaporation, and evaporite dissolution, largely in magmatic and basinal systems. Today, research is focused on establishing the concentrations of metals in these fluids, the volume and duration of hydrothermal flow, and the links between ore systems and larger, regional fluid systems.

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Fluids in Planetary Systems

At our first inaugural meeting last April, we sifted through several pages of potential topics. Some had been suggested by the councils of the par- ticipating societies; others had been gathered at meetings, while talking to colleagues. We strived to choose topics that would be of interest to a wide part of our membership – in each of these issues, mineralogists, geochemists, and petrologists should find at least one article of great interest to them – but also topics where exciting developments are underway. We also needed to find guest editors and authors willing to work under very tight deadlines. It you are interested in proposing a topic, you can download a propos- al form from our web site. We are already developing themes for 2006 and 2007. Here is what you can look forward to in 2005.

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The Role of Reducing Conditions in Building Mercury

Extremely reducing conditions, such as those that prevailed during the accretion and differentiation of Mercury, change the “normal” pattern of behaviour of many chemical elements. Lithophile elements can become chalcophile, siderophile elements can become lithophile, and volatile elements can become refractory. In this context, unexpected elements, such as Si, are extracted to the core, while others (S, C) concentrate in the silicate portion of the planet, eventually leading to an exotic surface mineralogy. In this article, experimental, theoretical and cosmochemical arguments are applied to the understanding of how reducing conditions influenced Mercury, from the nature of its building blocks to the dynamics of its volcanism.

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December 2025 --The Variscan Orogeny in Europe – Understanding Supercontinent Formation

The Variscan orogen formed between 380 and 300 million years ago through several accretionary and collisional cycles, culminating with the construction of the Pangea supercontinent. This process occurred via sequential opening and closure of oceanic basins, synchronous detachment of Gondwana derived continental ribbons, and their outboard amalgamation onto the Laurussia margin. The Variscan orogen is rather unique compared with other orogenic belts on Earth: its overthickened and dominantly magmatic crust in the central belt, surprisingly minor mantle involvement in the magmatic and geodynamic processes, coherent and pulsed magmatism along the collision suture, and its complex accretionary history. Because its final product, Pangea, is the youngest and best-understood supercontinent on Earth, the Variscan orogeny offers clues for understanding the mechanisms of supercontinent formation.