Thematic Articles

Oceanic LIPs: The Kiss of Death

Oceanic plateaus represent large areas (~1 ×× 106 km2) of thickened oceanic crust formed from rapidly erupted lava (<3 Myr). These plateaus have formed throughout most of geological time. They generally correlate with periods of environmental catastrophe characterised by oceanic anoxia, leading to black shale formation and mass extinction events. Such correlations are particularly evident in the Cretaceous and can be partly attributed to the release of CO2 during oceanic plateau formation, which ultimately resulted in a runaway greenhouse effect. Additionally, sea level rise and disruption of oceanic circulation patterns by displacement of seawater during plateau formation contributed to increased environmental stress and biotic extinction.

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Gas Fluxes from Flood Basalt Eruptions

Subaerial continental flood basalt volcanism is distinguished from all other volcanic activity by the repeated effusion of huge batches of basaltic magma (~102–103 km3 per eruption) over short periods of geologic time (<1 Myr). Flood basalt provinces are constructed of thick stacks of extensive pahoehoe-dominated lava flow fields and are the products of hundreds of eruptions. Each huge eruption comes from a dyke-fed fissure tens to hundreds of kilometres long and lasts about a decade or more. Such spatial and temporal patterns of lava production do not occur at any other time in Earth history, and, during eruptions, gas fluxes of ~1 Gt per year of SO2 and CO2 over periods of a decade or more are possible. Importantly, the atmospheric cooling associated with aerosols generated from the SO2 emis- sions of just one flood basalt eruption is likely to have been severe and would have persisted for a decade or longer. By contrast, warming due to volca- nogenic CO2 released during an eruption is estimated to have been insignifi- cant because the mass of CO2 would have been small compared to that already present in the atmosphere.

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Meteorite Impacts as Triggers to Large Igneous Provinces

Ameteorite impacting on the surface of the Earth produces not only a crater but also, if the impactor is sufficiently large, high melt volumes. Computer simulations suggest that, in addition to shock- induced melting produced by impact, additional decompression melting of the hot target mantle beneath the crater can produce melt volumes comparable to those found in large igneous provinces (LIPs). The coincidence between the expected frequency of such impact events combined with the similarity in magma volumes of LIPs suggests that large meteorite impacts may be capable of triggering LIPs and mantle hotspots from a point source which is subsequently buried. Can the impact model explain any LIP? What are the distinctive macroscopic criteria predicted from an impact model, and how may they be recognised or rejected in the geological record of the Earth?

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Large Igneous Provinces, Delamination, and Fertile Mantle

When continental crust gets too thick, the dense eclogitic bottom detaches, causing uplift, asthenospheric upwelling, and pressure- release melting. Delamination introduces warm blocks of lower crust with a low melting point into the mantle; these eventually heat up, ascend, decompress, and melt. The mantle below 100 km depth is mainly below the melting point of dry peridotite, but its temperature will be above the melting point of recycled fertile (basaltic or eclogitic) components, obviating the need for excess temperature to form “hotspots” or “melting anomalies”. When plates pull apart or delaminate, the mantle upwells; entrained crustal fragments of various ages are fertile and create melting anomalies along developing mid-ocean ridges, fracture zones, and old suture zones. Eclogites associated with delamination are warmer and less dense than subducted oceanic crust and more susceptible to melting and entrainment.

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Large Igneous Provinces and the Mantle Plume Hypothesis

Mantle plumes are columns of hot, solid material that originate deep in the mantle, probably at the core–mantle boundary. Laboratory and numerical models replicating conditions appropriate to the mantle show that mantle plumes have a regular and predictable shape that allows a number of testable predictions to be made. New mantle plumes are predicted to consist of a large head, 1000 km in diameter, followed by a narrower tail. Initial eruption of basalt from a plume head should be preceded by ~1000 m of domal uplift. High-temperature magmas are expected to dominate the first eruptive products of a new plume and should be concen- trated near the centre of the volcanic province. All of these predictions are confirmed by observations.

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Large Igneous Provinces: Origin and Environmental Consequences

Episodically, the Earth erupts large quantities of basaltic magma in geologically short periods of time. This results in the formation of large igneous provinces, which include continental flood basalt provinces, volcanic rifted margins, and giant oceanic plateaus. These fluctuations in the Earth’s system are still poorly understood. Do they owe their origin to mantle plumes, meteorite impacts, or lithosphere-controlled processes? Whatever their origin they correlate closely with major changes in oceanic and atmospheric chemistry and may trigger global mass extinctions.

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Trace Metal Retention on Biogenic Manganese Oxide Nanoparticles

Manganese oxides produced by microorganisms are abundant environ- mental nanoparticles whose high retention capacity for toxic trace metals, especially lead, is well established. Until very recently, our knowledge of the molecular-scale structure and reactivity of these biogenic Mn4+ oxide minerals was inferred from studies of synthetic analogues pre- pared in the laboratory. However, biogenic Mn oxides and their reactions with trace metals now can be investigated directly using X-ray absorption spectroscopy, thus bringing new insights into the molecular mechanisms behind the very high scavenging efficiency of these minerals. This new knowledge has important implications for the remediation of trace metal contamination.

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Synchrotron X-ray Investigations of Mineral–Microbe–Metal Interactions

Interactions between microbes and minerals can play an important role in metal transformations (i.e. changes to an element’s valence state, coordination chemistry, or both), which can ultimately affect that ele- ment’s mobility. Mineralogy affects microbial metabolism and ecology in a system; microbes, in turn, can affect the system’s mineralogy. Increasingly, synchrotron-based X-ray experiments are in routine use for determining an element’s valence state and coordination chemistry, as well as for examining the role of microbes in metal transformations.

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Shining Light on Metals in the Environment

Elucidating the speciation of heavy metals in the environment is para- mount to understanding their potential mobility and bioavailability. Cutting-edge synchrotron-based techniques such as microfocused X-ray absorption fine-structure (XAFS) and X-ray fluorescence (XRF) spectroscopy and microtomography have revolutionized the way metal reactions and processes in natural systems are studied. In this article, we apply these intense-light tools to decipher metal forms (species) and associations in contaminated soils and metal-hyperaccumulating plants.

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Metal Retention and Transport on Colloidal Particles in the Environment

Many potentially toxic trace metals and radionuclides are strongly adsorbed onto surfaces of mineral and organic compounds in soils and sediments, limiting their mobility in the environment. However, recent studies have shown that trace metals in soils, groundwater, rivers, and lakes can be carried by mobile colloidal particles. Understanding the release, transport, aggregation, and deposition of natural colloidal particles is there- fore of utmost importance for developing quantitative models of contami- nant transport and the biogeochemical cycling of trace metals.

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December 2025 --The Variscan Orogeny in Europe – Understanding Supercontinent Formation

The Variscan orogen formed between 380 and 300 million years ago through several accretionary and collisional cycles, culminating with the construction of the Pangea supercontinent. This process occurred via sequential opening and closure of oceanic basins, synchronous detachment of Gondwana derived continental ribbons, and their outboard amalgamation onto the Laurussia margin. The Variscan orogen is rather unique compared with other orogenic belts on Earth: its overthickened and dominantly magmatic crust in the central belt, surprisingly minor mantle involvement in the magmatic and geodynamic processes, coherent and pulsed magmatism along the collision suture, and its complex accretionary history. Because its final product, Pangea, is the youngest and best-understood supercontinent on Earth, the Variscan orogeny offers clues for understanding the mechanisms of supercontinent formation.