Thematic Articles

Kaolin-Group Minerals: From Hydrogen-Bonded Layers to Environmental Recorders

Kaolin-group minerals typically form as a result of hydrothermal alteration and/or weathering processes. They occur in environments as diverse as tropical soils, continental sedimentary deposits, and altered crustal rocks. They have also been detected on the surface of Mars. Given their prevalence, they have attracted the attention of researchers in materials chemistry, environmental geochemistry, and high-pressure mineral physics. Their structure and related properties have been studied for about a century, and these studies reflect advances in experimental techniques, modeling approaches, and concepts in mineralogy. Among key features of their structure are the predominance of 2-D stacking defects and the peculiar role of H-bonding in the control of their polytypism.

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Kaolin: From Ancient Porcelains to Nanocomposites

Kaolin has played a prominent role in both Earth and human cultural history, and will continue to do so into the foreseeable future. Its abundance in the rock record has varied according to the waxing and waning of life faunal radiations, crustal differentiation, and climatic conditions. Kaolin-group minerals play an important environmental role in soils of tropical and temperate regions. They also occur in hydrothermal zones, where they form at the expense of felsic rocks through acid hydrolysis, and commonly in episodic geologic events. Kaolin deposits form the basis of many modern materials, but the first sophisticated human use was in porcelains from Jingdezhen, China. From the initial discovery of kaolin and its sculptural use 2000 years ago to today’s modern applications in nanocomposites, kaolin has been important throughout cultural history. Art and science are intertwined by the properties and uses of this amazingly small clay mineral.

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Diamonds in Ophiolites

Ophiolites are a newly documented host of diamonds on Earth. Abundant diamonds have indeed been separated from peridotites and chromitites of ophiolites in China, Myanmar, and Russia. In addition, diamond grains have recently been discovered in chromite from the Cretaceous Luobusa ophiolite (Tibet) and the early Paleozoic Ray-Iz ophiolite (polar Urals, Russia). These diamonds are accompanied by a wide range of highly reduced minerals, such as Ni–Mn–Co alloys, Fe–Si and Fe–C phases, and moissanite (SiC); these have been found as either mineral separates or inclusions in diamonds and indicate growth under superreducing conditions. The diamond-bearing chromite grains likely formed near the mantle transition zone and were then brought to shallow levels in the upper mantle to form podiform chromitites in oceanic lithosphere. Because these diamond grains occur widely in peridotites and chromitites of many ophiolites, we refer to them as ophiolite-hosted diamonds. It is possible that such diamonds may be common in the upper oceanic mantle.

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Deep Biosphere Record of In Situ Oceanic Lithosphere and Ophiolites

Volcanic glass from pillow lavas and hyaloclastites displays distinctive alteration textures that suggest the activity of boring microbes. Analogous textures are common in volcanic sections of the seafloor, in ophiolites, and in greenstone belts up to 3.5 Ga in age. While the origin of such trace fossils remains poorly understood, they offer much potential for investigating processes in the present-day, deep-ocean, crustal biosphere and their role in biogeochemical cycles.

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Izu-Bonin-Mariana Forearc Crust as a Modern Ophiolite Analogue

Recent geological and geophysical surveys in the Izu-Bonin-Mariana forearc have revealed the occurrence on the seafl oor of oceanic crust generated in the initial stages of subduction and the earliest stage of island arc formation. The earliest magmatism after subduction initiation generated forearc basalts, and subsequently, boninitic and tholeiitic to calc-alkaline lavas were produced. Collectively, these rocks make up the extrusive sequence of the Izu-Bonin-Mariana forearc oceanic crust. This volcanic stratigraphy and its time-progressive development are analogous to those documented from many suprasubduction zone ophiolites. Most suprasubduction zone ophiolites may be on-land fragments of forearc oceanic crust, produced during the initiation of subduction and the early stages of island arc development.

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Records of Ocean Growth and Destruction in the Oman–UAE Ophiolite

The Oman–UAE ophiolite is the largest piece of oceanic crust exposed on land, yet debate continues about its origin. It has been variously considered as an ideal analogue for a fast-spreading mid-ocean ridge and as a typical suprasubduction zone ophiolite. A resolution to this conundrum comes from the recognition of at least two different phases of magmatism, with the second phase being most voluminous in the northern blocks of the ophiolite. The first phase was formed at an oceanic spreading centre; petrological and geochemical evidence clearly shows that the second phase was formed above a subduction zone.

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Immobile Element Fingerprinting of Ophiolites

Much of our understanding of ocean ridges has come from the collection and analysis of glasses recovered from ridge axes. However, applying the resulting methodologies to ophiolite complexes is not straightforward because ophiolites typically experience intense alteration during their passage from ridge to subduction zone to mountain belt. Instead, immobile element proxies for fractionation indices, alkalinity, mantle temperature, mantle flow and subduction addition may be used to classify ophiolite lavas and fingerprint the precise setting of the ridge at which an ophiolite formed. The results can help us recognise and interpret past spreading centres and so make plate tectonic reconstructions.

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Ophiolites and Their Origins

Ophiolites are suites of temporally and spatially associated ultramafic, mafic, and felsic rocks that are interpreted to be remnants of ancient oceanic crust and upper mantle. Ophiolites show significant variations in their internal structure, geochemical fingerprints, and emplacement mechanisms. These differences are controlled by (1) the proximity, when formed at the magmatic stage, to a plume or trench; (2) the rate, geometry, and nature of ocean-ridge spreading; (3) mantle composition, temperature, and fertility; and (4) the availability of fluids. The oceanic crust preserved in ophiolites may form in any tectonic setting during the evolution of ocean basins, from the rift–drift and seafloor spreading stages to subduction initiation and terminal closure. An ophiolite is emplaced either from downgoing oceanic lithosphere via subduction-accretion or from the upper plate in a subduction zone through trench–continent collision. Subduction zone tectonics is thus the most important factor in the igneous evolution of ophiolites and their emplacement into continental margins.

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Magnetic Guidance in Multicellular Prokaryotes and Eukaryotes

Some organisms have the unique capacity to geolocate and navigate in response to the Earth’s magnetic field lines. Migratory birds and fishes are the best-documented animals that evolved this capacity to guide their movements. In the microbial world, magnetotactic bacteria (MTB) and multicellular magnetotactic prokaryotes (MMPs) have been the only known magnetoreceptive microorganisms for decades. Some microeukaryotes also orient their motility axis along magnetic field lines thanks to the exploitation of MTB magnetism. The magnetic guidance of these prokaryotes and eukaryotes is due to the biomineralization of magnetic crystals. This article provides a brief overview of the current knowledge concerning the different multicellular prokaryotes and micro/macroeukaryotes capable of magnetoreception. We also discuss the evolution of this unique ability.

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Environmental, Biomedical, and Industrial Applications of Biogenic Magnetite Nanoparticles

Magnetite is the most abundant magnetic iron mineral on the Earth’s surface. Its formation in natural ecosystems is mainly due to microbial activity. Microbially synthesized magnetite, commonly called “biogenic magnetite,” has many beneficial properties for a wide range of environmental and commercial applications. Its high surface reactivity facilitates interactions with (in)organic pollutants in anthropic and natural ecosystems, as well as with reagents in industrial catalysis. Due to its magnetic properties and good biocompatibility, biogenic magnetite is also well suited for biomedical applications such as cancer treatment or drug delivery. Biomineralization of magnetite offers an inexpensive and sustainable method for the production of this highly functional material. Moreover, this biomineralization process results in a biomolecule coating of the magnetite, making it highly amenable to further functionalization. This chapter reviews the application of biogenic magnetite across environmental, medical, and industrial settings. Existing challenges and future opportunities in these applications are also discussed.

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December 2025 --The Variscan Orogeny in Europe – Understanding Supercontinent Formation

The Variscan orogen formed between 380 and 300 million years ago through several accretionary and collisional cycles, culminating with the construction of the Pangea supercontinent. This process occurred via sequential opening and closure of oceanic basins, synchronous detachment of Gondwana derived continental ribbons, and their outboard amalgamation onto the Laurussia margin. The Variscan orogen is rather unique compared with other orogenic belts on Earth: its overthickened and dominantly magmatic crust in the central belt, surprisingly minor mantle involvement in the magmatic and geodynamic processes, coherent and pulsed magmatism along the collision suture, and its complex accretionary history. Because its final product, Pangea, is the youngest and best-understood supercontinent on Earth, the Variscan orogeny offers clues for understanding the mechanisms of supercontinent formation.